Übergangsmetall- und Lanthanoid-Komplexe von 1,4,7,10-Tetraallylund 1,4,7,10-Tetra-3-butenyl-1,4,7,10-tetraazacyclododecan
| dc.contributor.author | Schumann, Herbert | |
| dc.contributor.author | Kuse, Katharina | |
| dc.contributor.author | Hummert, Markus | |
| dc.contributor.author | Pickardt, Joachim | |
| dc.date.accessioned | 2018-10-01T14:43:25Z | |
| dc.date.available | 2018-10-01T14:43:25Z | |
| dc.date.issued | 2009 | |
| dc.description.abstract | 1,4,7,10-Tetraazacyclododecane (1) reacts with allylbromide and 3-butenylbromide giving 1,4,7,10-tetraallyl-1,4,7,10-tetraazacyclododecane (TAC) (2a) and 1,4,7,10-tetra-3-butenyl-1,4,7,10- tetraazacyclododecane (TBC) (2b), respectively. Compounds 2a and 2b react with FeCl2, CoCl2, RhCl3, NiCl2, CuBr2, and TmCl3 forming the complexes [FeCl(TAC)]Cl (3a), [FeCl(TBC)]Cl (3b), [CoCl(TAC)]Cl (4), [RhCl(TAC)]Cl2 (5), [NiCl(TAC)]Cl (6a), [NiCl(TBC)]Cl (6b), [CuBr(TAC)]Br (7), [TmCl(TAC)]Cl2 (8a), and [TmCl(TBC)]Cl2 (8b). The reaction of 6a with an excess of CuCl affords a coordination polymer in which [NiCl(TAC)]+ cations are connected by [Cu6Cl8]2− anions (9). The 1H and 13C NMR spectra of 2a, 2b, 5, and 6a, as well as the single crystal X-ray structures of 2a ・3HCl, 6a, 6b, 7, and 9 are reported and discussed. | en |
| dc.identifier.eissn | 1865-7117 | |
| dc.identifier.issn | 0932-0776 | |
| dc.identifier.uri | https://depositonce.tu-berlin.de/handle/11303/8245 | |
| dc.identifier.uri | http://dx.doi.org/10.14279/depositonce-7396 | |
| dc.language.iso | de | |
| dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/3.0/ | |
| dc.subject.ddc | 540 Chemie und zugeordnete Wissenschaften | de |
| dc.subject.other | Tetraazacyclododecane | en |
| dc.subject.other | Cobalt | en |
| dc.subject.other | Copper | en |
| dc.subject.other | Iron | en |
| dc.subject.other | Nickel | en |
| dc.subject.other | Rhodium | en |
| dc.subject.other | Thulium | en |
| dc.subject.other | complexes | en |
| dc.title | Übergangsmetall- und Lanthanoid-Komplexe von 1,4,7,10-Tetraallylund 1,4,7,10-Tetra-3-butenyl-1,4,7,10-tetraazacyclododecan | de |
| dc.title.translated | Transition Metal and Lanthanide Complexes of 1,4,7,10-Tetraallyl- and 1,4,7,10-Tetra-3-butenyl- 1,4,7,10-tetraazacyclododecane | en |
| dc.type | Article | en |
| dc.type.version | publishedVersion | en |
| dcterms.bibliographicCitation.doi | 10.1515/znb-2009-0112 | |
| dcterms.bibliographicCitation.issue | 1 | |
| dcterms.bibliographicCitation.journaltitle | Zeitschrift für Naturforschung B | de |
| dcterms.bibliographicCitation.originalpublishername | De Gruyter | en |
| dcterms.bibliographicCitation.originalpublisherplace | Berlin | en |
| dcterms.bibliographicCitation.pageend | 100 | |
| dcterms.bibliographicCitation.pagestart | 93 | |
| dcterms.bibliographicCitation.volume | 64 | |
| tub.accessrights.dnb | free | |
| tub.affiliation | Fak. 2 Mathematik und Naturwissenschaften::Inst. Chemie | de |
| tub.affiliation.faculty | Fak. 2 Mathematik und Naturwissenschaften | de |
| tub.affiliation.institute | Inst. Chemie | de |
| tub.publisher.universityorinstitution | Technische Universität Berlin | de |
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