Metallkomplexe mit Hexamethylentetramin als Ligand, VI [1] Kristallstruktur von Bis-hexamethylentetramin-bisisocyanatokupfer(II), [CU(NCO)2(C6H12N4)2]hexamethylenetetramine-bisisocyanatocopper(II), [Cu(NCO)2(C6Hl2N4)2]

Pickardt, Joachim; Rautenberg, Norbert

Metallkomplexe mit Hexamethylentetramin als Ligand, VI [1] Kristallstruktur von Bis-hexamethylentetramin-bisisocyanatokupfer(II), [CU(NCO)2(C6H12N4)2]hexamethylenetetramine-bisisocyanatocopper(II), [Cu(NCO)2(C6Hl2N4)2]

dc.contributor.author	Pickardt, Joachim
dc.contributor.author	Rautenberg, Norbert
dc.date.accessioned	2019-01-02T14:02:50Z
dc.date.available	2019-01-02T14:02:50Z
dc.date.issued	1982
dc.description.abstract	Crystals of the complex [Cu(NCO)2(C6Hi2N4)2] could be obtained by reaction of copper- (II)nitrate, hexamethylenetetramine, and KNCO in CHCI3 as a solvent. The crystals are triclinic, space group Cl, Z = 4, a = 1373.1(9), b = 2083.1(9), c = 642.6(3) pm, a = 91.05(4), β = 90.54(6), y = 107.39(6)°. The copper atom is bonded to two terminal cyanato groups via the nitrogen atoms, and to two liexamethylentetramine molecules. In the solid state the coordination of the copper atom is, however, tetragonal pyramidal, because there is an additional, rather long bond to one of the hexamethylenetetramine molecules of the neighbouring complex unit, resulting in the formation of chains.	en
dc.identifier.eissn	1865-7117
dc.identifier.issn	0932-0776
dc.identifier.uri	https://depositonce.tu-berlin.de/handle/11303/8785
dc.identifier.uri	http://dx.doi.org/10.14279/depositonce-7914
dc.language.iso	de
dc.rights.uri	https://creativecommons.org/licenses/by-nc-nd/3.0/
dc.subject.ddc	540 Chemie und zugeordnete Wissenschaften	de
dc.subject.other	cupric complexes	en
dc.subject.other	isocyanato complexes	en
dc.subject.other	hexamethylenetetramine	en
dc.subject.other	crystal structure	en
dc.title	Metallkomplexe mit Hexamethylentetramin als Ligand, VI [1] Kristallstruktur von Bis-hexamethylentetramin-bisisocyanatokupfer(II), [CU(NCO)2(C6H12N4)2]hexamethylenetetramine-bisisocyanatocopper(II), [Cu(NCO)2(C6Hl2N4)2]	de
dc.title.translated	Metal Complexes with Hexamethylenetetramine as a Ligand, VI [1J Crystal Structure of Bis-hexamethylenetetramine-bisisocyanatocopper(II), [Cu(NCO)2(C6Hl2N4)2]	de
dc.type	Article	en
dc.type.version	publishedVersion	en
dcterms.bibliographicCitation.doi	10.1515/znb-1982-1216
dcterms.bibliographicCitation.issue	12
dcterms.bibliographicCitation.journaltitle	Zeitschrift für Naturforschung B	de
dcterms.bibliographicCitation.originalpublishername	De Gruyter	en
dcterms.bibliographicCitation.originalpublisherplace	Berlin
dcterms.bibliographicCitation.pageend	1572
dcterms.bibliographicCitation.pagestart	1569
dcterms.bibliographicCitation.volume	37
tub.accessrights.dnb	free
tub.affiliation	Fak. 2 Mathematik und Naturwissenschaften::Inst. Chemie::FG Anorganische Chemie - Festkörper- und Materialchemie	de
tub.affiliation.faculty	Fak. 2 Mathematik und Naturwissenschaften	de
tub.affiliation.group	FG Anorganische Chemie - Festkörper- und Materialchemie	de
tub.affiliation.institute	Inst. Chemie	de
tub.publisher.universityorinstitution	Technische Universität Berlin	de

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