Synthesis of a cyclopentadienyl(imino)stannylene and its direct conversion into halo(imino)stannylenes
| dc.contributor.author | Ochiai, Tatsumi | |
| dc.contributor.author | Inoue, Shigeyoshi | |
| dc.date.accessioned | 2018-04-19T08:47:49Z | |
| dc.date.available | 2018-04-19T08:47:49Z | |
| dc.date.issued | 2017 | |
| dc.description.abstract | The reaction of stannocene Cp2Sn with iminolithium LiNIPr (NIPr = bis(2,6-diisopropylphenyl)imidazolin-2-iminato) afforded the dimeric cyclopentadienyl(imino)stannylene [(η1-Cp)SnNIPr]2 (1). Compound 1 exhibits unexpected reactivity towards haloalkanes. The high-yield conversion of 1 into chlorostannylene [ClSnNIPr]2 (2) and bromostannylene [BrSnNIPr]2 (3) were accomplished by treatment with dichloromethane or 1,2-dibromoethane, respectively, through a Cp-substitution reaction. | en |
| dc.identifier.eissn | 2046-2069 | |
| dc.identifier.issn | 2046-2069 | |
| dc.identifier.uri | https://depositonce.tu-berlin.de/handle/11303/7645 | |
| dc.identifier.uri | http://dx.doi.org/10.14279/depositonce-6835 | |
| dc.language.iso | en | |
| dc.rights.uri | https://creativecommons.org/licenses/by/3.0/ | |
| dc.subject.ddc | 540 Chemie und zugeordnete Wissenschaften | |
| dc.title | Synthesis of a cyclopentadienyl(imino)stannylene and its direct conversion into halo(imino)stannylenes | en |
| dc.type | Article | |
| dc.type.version | publishedVersion | en |
| dcterms.bibliographicCitation.doi | 10.1039/c6ra27697k | |
| dcterms.bibliographicCitation.issue | 2 | |
| dcterms.bibliographicCitation.journaltitle | RSC Advances | en |
| dcterms.bibliographicCitation.originalpublishername | Royal Society of Chemistry (RSC) | |
| dcterms.bibliographicCitation.originalpublisherplace | London | |
| dcterms.bibliographicCitation.pageend | 804 | |
| dcterms.bibliographicCitation.pagestart | 801 | |
| dcterms.bibliographicCitation.volume | 7 | |
| tub.accessrights.dnb | free | |
| tub.affiliation | Fak. 2 Mathematik und Naturwissenschaften::Inst. Chemie::FG Metallorganische Chemie und Anorganische Materialien | de |
| tub.affiliation.faculty | Fak. 2 Mathematik und Naturwissenschaften | de |
| tub.affiliation.group | FG Metallorganische Chemie und Anorganische Materialien | de |
| tub.affiliation.institute | Inst. Chemie | de |
| tub.publisher.universityorinstitution | Technische Universität Berlin | de |
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