Exceptional long-life performance of lithium-ion batteries using ionic liquid-based electrolytes

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dc.contributor.authorElia, Giuseppe Antonio
dc.contributor.authorUlissi, Ulderico
dc.contributor.authorJeong, Sangsik
dc.contributor.authorPasserini, Stefano
dc.contributor.authorHassoun, Jusef
dc.date.accessioned2017-10-24T07:15:11Z
dc.date.available2017-10-24T07:15:11Z
dc.date.issued2016
dc.descriptionDieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich.de
dc.descriptionThis publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.en
dc.description.abstractAdvanced ionic liquid-based electrolytes are herein characterized for application in high performance lithium-ion batteries. The electrolytes based on either N-butyl-N-methylpyrrolidinium bis(trifluoromethanesulfonyl) imide (Pyr(14)TFSI), N-butyl-N-methylpyrrolidinium bis(fluoro-sulfonyl) imide (Pyr(14)FSI), N-methoxy-ethyl-N-methylpyrrolidinium bis(trifluoromethane-sulfonyl) imide (Pyr(12O1)TFSI) or N-N-diethyl-N-methyl-N-(2methoxyethyl) ammonium bis(trifluoromethanesulfonyl) imide (DEMETFSI) ionic liquids and lithium bis(trifluoromethanesulfonyl) imide (LiTFSI) salt are fully characterized in terms of ionic conductivity, viscosity, electrochemical properties and lithium-interphase stability. All IL-based electrolytes reveal suitable characteristics for application in batteries. Lithium half-cells, employing a LiFePO4 polyanionic cathode, show remarkable performance. In particular, relevant efficiency and rate-capability are observed for the Py14FSI-LiTFSI electrolyte, which is further characterized for application in a lithium-ion battery composed of the alloying Sn-C nanocomposite anode and LiFePO4 cathode. The IL-based full-cell delivers a maximum reversible capacity of about 160 mA h g(-1) (versus cathode weight) at a working voltage of about 3 V, corresponding to an estimated practical energy of about 160 W h kg(-1). The cell evidences outstanding electrochemical cycle life, i.e., extended over 2000 cycles without signs of decay, and satisfactory rate capability. This performance together with the high safety provided by the IL-electrolyte, olivine-structure cathode and Li-alloying anode, makes this cell chemistry well suited for application in new-generation electric and electronic devices.en
dc.identifier.eissn1754-5706
dc.identifier.issn1754-5692
dc.identifier.urihttps://depositonce.tu-berlin.de/handle/11303/6893
dc.identifier.urihttp://dx.doi.org/10.14279/depositonce-6232
dc.language.isoen
dc.rights.urihttp://rightsstatements.org/vocab/InC/1.0/
dc.subject.ddc690 Hausbau, Bauhandwerkde
dc.titleExceptional long-life performance of lithium-ion batteries using ionic liquid-based electrolytesen
dc.typeArticleen
dc.type.versionpublishedVersionen
dcterms.bibliographicCitation.doi10.1039/c6ee01295g
dcterms.bibliographicCitation.issue10
dcterms.bibliographicCitation.journaltitleEnergy & environmental scienceen
dcterms.bibliographicCitation.originalpublishernameRoyal Society of Chemistryde
dcterms.bibliographicCitation.originalpublisherplaceCambridgede
dcterms.bibliographicCitation.pageend3220
dcterms.bibliographicCitation.pagestart3210
dcterms.bibliographicCitation.volume9
tub.accessrights.dnbdomain
tub.affiliationFak. 4 Elektrotechnik und Informatik::Inst. Hochfrequenz- und Halbleiter-Systemtechnologien::FG Nano Interconnect Technologiesde
tub.affiliation.facultyFak. 4 Elektrotechnik und Informatikde
tub.affiliation.groupFG Nano Interconnect Technologiesde
tub.affiliation.instituteInst. Hochfrequenz- und Halbleiter-Systemtechnologiende
tub.publisher.universityorinstitutionTechnische Universität Berlin

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