Molekül- und Kristallstruktur von 1.1-Dimethylsilylentitanocendichlorid, (CH3)2Si(C5H4)2TiCl2
dc.contributor.author | Köpf, Hartmut | |
dc.contributor.author | Pickardt, Joachim | |
dc.date.accessioned | 2019-01-04T13:17:01Z | |
dc.date.available | 2019-01-04T13:17:01Z | |
dc.date.issued | 1981 | |
dc.description.abstract | The molecular structure of the bridged [1]-titanocenophane 1,1'-dimethylsilylene titanocene dichloride, (CH3)2Si(C5H4)2TiCl2, has been investigated by an X-ray structure determination. Crystal data: monoclinic, space group C2/c, Z = 4, a = 1332.9(3), 6 = 988.7(3), c = 1068.9(3) pm, β = 113.43(2)°. The results are compared with the structural dimensions of similar compounds: 1,1'-methylene titanocene dichloride, CH2(C5H4)TiCl2, with the unbridged titanocene dichloride, (C5H5)2TiCl2 and the ethylene-bridged compound (CH2)2(C5H4)2TiCl2. | en |
dc.identifier.eissn | 1865-7117 | |
dc.identifier.issn | 0932-0776 | |
dc.identifier.uri | https://depositonce.tu-berlin.de/handle/11303/8796 | |
dc.identifier.uri | http://dx.doi.org/10.14279/depositonce-7925 | |
dc.language.iso | de | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/3.0/ | |
dc.subject.ddc | 540 Chemie und zugeordnete Wissenschaften | de |
dc.subject.other | [l]-titanocenophane | en |
dc.subject.other | 1,1'-dimethylsilylene titanocene dichloride | en |
dc.subject.other | molecular structure | en |
dc.subject.other | x-ray | en |
dc.title | Molekül- und Kristallstruktur von 1.1-Dimethylsilylentitanocendichlorid, (CH3)2Si(C5H4)2TiCl2 | de |
dc.title.translated | Molecular and Crystal Structure of l,r-Dimethylsilylene Titanocene Dichloride, (CH3)2Si(C5H4)2TiCl2 | de |
dc.type | Article | en |
dc.type.version | publishedVersion | en |
dcterms.bibliographicCitation.doi | 10.1515/znb-1981-1002 | |
dcterms.bibliographicCitation.issue | 10 | |
dcterms.bibliographicCitation.journaltitle | Zeitschrift für Naturforschung B | de |
dcterms.bibliographicCitation.originalpublishername | De Gruyter | en |
dcterms.bibliographicCitation.originalpublisherplace | Berlin | |
dcterms.bibliographicCitation.pageend | 1210 | |
dcterms.bibliographicCitation.pagestart | 1208 | |
dcterms.bibliographicCitation.volume | 36 | |
tub.accessrights.dnb | free | |
tub.affiliation | Fak. 2 Mathematik und Naturwissenschaften::Inst. Chemie::FG Anorganische Chemie - Festkörper- und Materialchemie | de |
tub.affiliation.faculty | Fak. 2 Mathematik und Naturwissenschaften | de |
tub.affiliation.group | FG Anorganische Chemie - Festkörper- und Materialchemie | de |
tub.affiliation.institute | Inst. Chemie | de |
tub.publisher.universityorinstitution | Technische Universität Berlin | de |
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