Bixbyite-type phases in the system Ta-Zr-O-N
| dc.contributor.author | Lüdtke, Tobias Clemens | |
| dc.contributor.author | Orthmann, Steven | |
| dc.contributor.author | Lerch, Martin | |
| dc.date.accessioned | 2017-12-23T10:46:29Z | |
| dc.date.available | 2017-12-23T10:46:29Z | |
| dc.date.issued | 2017 | |
| dc.description.abstract | Phase-pure tantalum/zirconium oxide nitrides and nitrides were synthesized by the ammonolysis of amorphous oxide precursors. The nitrogen-rich oxide nitrides with variable anion composition and the nitride TaZrN3 crystallize in the cubic bixbyite-type structure (space group Ia3̅). The nitrogen content of these compounds has a significant influence on the cell parameters, the atomic positions, and the optical band gap. The results extend the already well-studied Ta–Zr–O–N system by new oxide nitrides in addition to the already known baddeleyite- and anosovite-type phases. TaZrN3 can be considered as a thermodynamically stable ternary variant of metastable Ta2N3. | en |
| dc.identifier.issn | 0340-4811 | |
| dc.identifier.uri | https://depositonce.tu-berlin.de/handle/11303/7302 | |
| dc.identifier.uri | http://dx.doi.org/10.14279/depositonce-6575 | |
| dc.language.iso | en | en |
| dc.relation.ispartof | 10.14279/depositonce-6027 | |
| dc.rights.uri | http://rightsstatements.org/vocab/InC/1.0/ | en |
| dc.subject.ddc | 546 Anorganische Chemie | de |
| dc.subject.other | bixbyite | en |
| dc.subject.other | nitride | en |
| dc.subject.other | oxide nitride | en |
| dc.subject.other | tantalum | en |
| dc.subject.other | zirconium | en |
| dc.title | Bixbyite-type phases in the system Ta-Zr-O-N | en |
| dc.type | Article | en |
| dc.type.version | publishedVersion | en |
| dcterms.bibliographicCitation.doi | 10.1515/znb-2017-0014 | en |
| dcterms.bibliographicCitation.issue | 4 | en |
| dcterms.bibliographicCitation.journaltitle | Zeitschrift für Naturforschung B | en |
| dcterms.bibliographicCitation.originalpublishername | DeGruyter | en |
| dcterms.bibliographicCitation.originalpublisherplace | Berlin | en |
| dcterms.bibliographicCitation.pageend | 311 | en |
| dcterms.bibliographicCitation.pagestart | 305 | en |
| dcterms.bibliographicCitation.volume | 72 | en |
| tub.accessrights.dnb | domain | * |
| tub.affiliation | Fak. 2 Mathematik und Naturwissenschaften::Inst. Chemie::FG Anorganische Chemie - Festkörper- und Materialchemie | de |
| tub.affiliation.faculty | Fak. 2 Mathematik und Naturwissenschaften | de |
| tub.affiliation.group | FG Anorganische Chemie - Festkörper- und Materialchemie | de |
| tub.affiliation.institute | Inst. Chemie | de |
| tub.publisher.universityorinstitution | Technische Universität Berlin | en |