Frontorbitale und 1.2-Hydridwanderungen in Carbeniumionen

Frenking, Gernot; Schwarz, Helmut

Frontorbitale und 1.2-Hydridwanderungen in Carbeniumionen

dc.contributor.author	Frenking, Gernot
dc.contributor.author	Schwarz, Helmut
dc.date.accessioned	2019-01-04T13:17:28Z
dc.date.available	2019-01-04T13:17:28Z
dc.date.issued	1981
dc.description.abstract	For various carbenium ions it is shown that the energy value and the degree of localization of the LUMO have a significant influence on the energy barriers of 1,2-hydrogen shifts. The structures of the transition states are in line with the Hammond-Postulate.	en
dc.identifier.eissn	1865-7117
dc.identifier.issn	0932-0776
dc.identifier.uri	https://depositonce.tu-berlin.de/handle/11303/8803
dc.identifier.uri	http://dx.doi.org/10.14279/depositonce-7932
dc.language.iso	de
dc.rights.uri	https://creativecommons.org/licenses/by-nc-nd/3.0/
dc.subject.ddc	540 Chemie und zugeordnete Wissenschaften	de
dc.subject.other	carbocation chemistry	en
dc.subject.other	1,2-hydrogen migration	en
dc.subject.other	frontier orbitals	en
dc.subject.other	quantum mechanical calculations	en
dc.subject.other	transition states	en
dc.title	Frontorbitale und 1.2-Hydridwanderungen in Carbeniumionen	de
dc.title.translated	Frontier Orbitals and 1,2-Hydrogen Shifts in Carbenium Ions	de
dc.type	Article	en
dc.type.version	publishedVersion	en
dcterms.bibliographicCitation.doi	10.1515/znb-1981-0705
dcterms.bibliographicCitation.issue	7
dcterms.bibliographicCitation.journaltitle	Zeitschrift für Naturforschung B	de
dcterms.bibliographicCitation.originalpublishername	De Gruyter	en
dcterms.bibliographicCitation.originalpublisherplace	Berlin
dcterms.bibliographicCitation.pageend	801
dcterms.bibliographicCitation.pagestart	797
dcterms.bibliographicCitation.volume	36
tub.accessrights.dnb	free
tub.affiliation	Fak. 2 Mathematik und Naturwissenschaften::Inst. Chemie::FG Organische Chemie	de
tub.affiliation.faculty	Fak. 2 Mathematik und Naturwissenschaften	de
tub.affiliation.group	FG Organische Chemie	de
tub.affiliation.institute	Inst. Chemie	de
tub.publisher.universityorinstitution	Technische Universität Berlin	de

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