Zhang, LiangliangOestreich, Martin2022-03-312022-03-312021-07-161433-7851https://depositonce.tu-berlin.de/handle/11303/16618http://dx.doi.org/10.14279/depositonce-15395A nickel/zinc‐catalyzed cross‐electrophile coupling of alkyl electrophiles activated by an α‐cyano group and chlorosilanes is reported. Elemental zinc is the stoichiometric reductant in this reductive coupling process. By this, a C(sp3)−Si bond can be formed starting from two electrophilic reactants whereas previous methods rely on the combination of carbon nucleophiles and silicon electrophiles or vice versa.en540 Chemie und zugeordnete Wissenschaftencross-couplingnickelsiliconsynthetic methodszincArticle2022-03-211521-3773