Steudel, RalfSteidel, JürgenRautenberg, Norbert2019-01-042019-01-0419800932-0776https://depositonce.tu-berlin.de/handle/11303/8807http://dx.doi.org/10.14279/depositonce-7936A redetermination of the crystal and molecular structure of the chain-like molecule S(NSO)2 resulted in the following molecular parameters: d(SO) = 146.5(2), d(S = N) = 153.4(2), d(S-N) = 165.7(2) pm, bond angles OSN = 117.5(1)°, SNS = 123.6(2)°, and NSN = 97.2(1)°, torsion angles OSNS = -0.3(2)°, and SNSN = -177.7(2)° (molecular symmetry C2). Infrared and Raman spectra of S(NSO)2 are reported and assigned; there is no evidence for conformational changes on dissolution of crystalline S(NSO)2.de540 Chemie und zugeordnete Wissenschaftensulfur nitrogen compoundsstructure|vibrational spectraArticle1865-7117