Ochiai, TatsumiFranz, DanielWu, Xiao-NanInoue, Shigeyoshi2017-10-252017-10-2520151477-9226https://depositonce.tu-berlin.de/handle/11303/6951http://dx.doi.org/10.14279/depositonce-6290Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich.This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.The novel amino(imino)germylene 1 was prepared by the conversion of HNIPr (NIPr = bis(2,6-diisopropylphenyl) imidazolin-2-imino) with 1 equiv. of Ge[N(SiMe3)(2)](2). Germylene 1 reacts with B (C6F5)(3) to afford the borate salt 2(+)[MeB(C6F5)(3)](-) in a methyl-abstraction and ring-closing reaction. The conversion of 2 with Fe-2(CO)(9) furnishes the germylene iron carbonyl complex 3 with a trigonal planar-coordinate germanium atom.en540 Chemie und zugeordnete WissenschaftenArticle1477-923426011737