Carrero, CarlosKauer, MarkusDinse, ArneWolfram, TillHamilton, NeilTrunschke, AnnetteSchlögl, RobertSchomäcker, Reinhard2016-06-232016-06-232014https://depositonce.tu-berlin.de/handle/11303/5612http://dx.doi.org/10.14279/depositonce-5241Grafted VxOy catalysts for oxidative dehydrogenation of propane (ODP) have been studied due to their potential high performance and as model catalysts in the past. We report on a positive synergetic effect capable of considerably enhancing the propene productivities above reported performances. The most productive catalysts were found at metal loadings (V + Ti) close to the monolayer coverage. The 4V/13Ti/SBA-15 catalyst presented a considerably high productivity (6–9 kgpropene kgcat−1 h−1). Moreover, with this catalyst, propene productivity only slightly decreased as a function of propane conversion, indicating that propene combustion toward COx occurs more slowly in comparison to other catalysts exhibiting high propene productivities. A detailed kinetic analysis of the 4V/13Ti/SBA-15 catalyst revealed that high vanadia and titania dispersions are required for high propene productivity.en540 Chemie und zugeordnete WissenschaftenArticle2044-4753