Bock, SörenEaves, Samantha G.Parthey, MatthiasKaupp, MartinGuennic, Boris leHalet, Jean-FrançoisYufit, Dmitry S.Howard, Judith A. K.Low, Paul J.2016-06-272016-06-272013https://depositonce.tu-berlin.de/handle/11303/5663http://dx.doi.org/10.14279/depositonce-5283Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich.This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.Convenient preparative routes to mononuclear ruthenium complexes containing the 2,4-pentadiynylnitrile, or cyanobutadiynyl, ligand are described. The electronic properties of the [C5N]− ligand are closely related to those of not only the cyanide ([CN]−) and 2-propynylnitrile or cyanoacetylide ([C[triple bond, length as m-dash]CC[triple bond, length as m-dash]N]−) ligands, but also those of the isoelectronic polyynyl ([{C[triple bond, length as m-dash]C}nR]−) ligands.en540 Chemie und zugeordnete WissenschaftenArticle1477-922623396403