Breit, Nora C.Eisenhut, CarstenInoue, Shigeyoshi2017-10-242017-10-2420161359-7345https://depositonce.tu-berlin.de/handle/11303/6907http://dx.doi.org/10.14279/depositonce-6246A dihydrophosphinosilylene iron complex [LSi{Fe(CO)(4)}PH2] has been prepared and utilized in the synthesis of novel heterobimetallic complexes. The phosphine moiety in this phosphinosilylene complex allows coordination towards tungsten leading to the iron-tungsten heterobimetallic complex [LSi{Fe(CO)(4)}PH2{W(CO)(5)}]. In contrast, the reaction of [LSi{Fe(CO)(4)}PH2] with ethylenebis(triphenylphosphine)platinum(0) results in the formation of the iron-platinum heterobimetallic complex [LSi{Fe(CO)(4)}PH{PtH(PPh3)(2)}] via oxidative addition.en540 Chemie und zugeordnete WissenschaftenArticle1364-548X26974121