Todorovic, SmiljaHildebrandt, PeterMartins, Ligia O.2017-10-252017-10-2520151463-9076https://depositonce.tu-berlin.de/handle/11303/6962http://dx.doi.org/10.14279/depositonce-6301Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich.This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.We report herein the vibrational spectroscopic characterisation of a catalytic intermediate formed by the reaction of H2O2 with DyP-type peroxidase immobilised on a biocompatible coated metal support. The SERR spectroscopic approach is of general applicability to other peroxidases which form relatively stable catalytic intermediates.en540 Chemie und zugeordnete WissenschaftenArticle1463-908425877022