Metallorganische Verbindungen der Lanthanoide, 41 [1]. Die Kristall-und Molekülstruktur von (C5Me5)2HoCl(THF)

Schumann, HerbertLoebel, J.Helm, D. van derHossain, M. B.2019-01-022019-01-0219880932-0776https://depositonce.tu-berlin.de/handle/11303/8757http://dx.doi.org/10.14279/depositonce-7886The title compound (1) is obtained as brownish crystals by reaction of HOCl3 with NaC5Me5 in tetrahydrofuran. The structure of 1, which has two slightly different independent molecules per asymmetric unit, has been elucidated by X-ray analysis. The crystals are triclinic with a = 1686.2(8) pm, b = 1816(1) pm, c = 846.5(4) pm, α = 92.02(7)°, β = 92.47(9)°, γ = 63.21(5)°, space group P1̄, D(calcd) = 1.560 g/cm3, and R = 0.0286, for 6219 observed reflections with I > 3σ(I).de540 Chemie und zugeordnete Wissenschaftenchloro-bis(pentamethylcyclopentadienyl)(tetrahydrofuran)holmium(iii)synthesisx-rayMetallorganische Verbindungen der Lanthanoide, 41 [1]. Die Kristall-und Molekülstruktur von (C5Me5)2HoCl(THF)Article1865-7117Organometallic Compounds of the Lanthanides, 41 [1]. The Crystal and Molecular Structure of (C5Me5)2HoCl(THF)