Köpf, HartmutRichtering, Verena2019-01-022019-01-0219880932-0776https://depositonce.tu-berlin.de/handle/11303/8758http://dx.doi.org/10.14279/depositonce-7887The reaction of the metallocene dichlorides Cp2MCl2 (Cp = η5-C5H5; M = Mo, W) with equimolar amounts of dilithium-o-phenylenebis(phenylphosphide) 1,2-(LiPPh)2C6H4 yields the five-membered chelate complexes Cp2M[1,2-(PPh)2C6H4] (M = Mo. 1; W, 2). Compounds 1 and 2 are characterized by IR, NMR and mass spectra.de540 Chemie und zugeordnete Wissenschaftenmetallocene complexeso-phenylenebis(phenylphosphido) chelatesbis(η5-cyclopentachenyl)-o-phenylenebis(phenylphosphane)diato-p,p'-molybdenum(IV)bis(η5-cyclopentadienyl)-o-phenylenebis(phenylphosphane)diato-p,p'-tungsten(IV)Article1865-7117