Köpf, HartmutPickardt, Joachim2019-01-042019-01-0419810932-0776https://depositonce.tu-berlin.de/handle/11303/8796http://dx.doi.org/10.14279/depositonce-7925The molecular structure of the bridged [1]-titanocenophane 1,1'-dimethylsilylene titanocene dichloride, (CH3)2Si(C5H4)2TiCl2, has been investigated by an X-ray structure determination. Crystal data: monoclinic, space group C2/c, Z = 4, a = 1332.9(3), 6 = 988.7(3), c = 1068.9(3) pm, β = 113.43(2)°. The results are compared with the structural dimensions of similar compounds: 1,1'-methylene titanocene dichloride, CH2(C5H4)TiCl2, with the unbridged titanocene dichloride, (C5H5)2TiCl2 and the ethylene-bridged compound (CH2)2(C5H4)2TiCl2.de540 Chemie und zugeordnete Wissenschaften[l]-titanocenophane1,1'-dimethylsilylene titanocene dichloridemolecular structurex-rayArticle1865-7117